2-Bromo-3,4,4-trichlorobut-3-enoates of certain natural alcohols, phenols, and oximes of carbonyl compounds |
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| Authors: | E A Dikusar V I Potkin N G Kozlov S K Petkevich N V Kovganko |
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| Institution: | (1) Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus’, Minsk, ul. Surganova, 13, Belarus;(2) Institute of Bioorganic Chemistry, National Academy of Sciences of Belarus’, Minsk, ul. Akad. Kuprevicha, 5/2, Belarus |
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| Abstract: | Previously undescribed 2-bromo-3,4,4-trichlorobut-3-enoates 1b-23b were synthesized in 84–91% yield from natural alcohols including terpenes and steroids, plant phenols, and oximes of natural
carbonyl compounds 1a-23a by reaction of 2-bromo-3,4,4-trichlorobut-3-enoyl chloride in the presence of pyridine.
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Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 212–215, May–June, 2006. |
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| Keywords: | 2-bromo-3 4 4-trichlorobut-3-enoyl chloride 2-bromo-3 4 4-trichlorobut-3-enoates esters terpene alcohols steroidal alcohols plant phenols oximes chemical modification |
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