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The role of peroxo complexes in the catalytic decomposition of H2O2 in the presence of Cu(II) hydroxides
Authors:G. L. Elizarova  L. G. Matvienko  O. L. Ogorodnikova  V. N. Parmon
Affiliation:(1) Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, 630090 Novosibirsk, Russia
Abstract:The catalytic decomposition of hydrogen peroxide is studied in the presence of colloidal and silicagel-supported Cu(OH)2. Copper peroxo complexes with different activities were identified. The reaction is molecular without radical formation. The mechanisms of H2O2 decomposition are discussed.
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