The role of peroxo complexes in the catalytic decomposition of H2O2 in the presence of Cu(II) hydroxides |
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Authors: | G. L. Elizarova L. G. Matvienko O. L. Ogorodnikova V. N. Parmon |
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Affiliation: | (1) Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, 630090 Novosibirsk, Russia |
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Abstract: | The catalytic decomposition of hydrogen peroxide is studied in the presence of colloidal and silicagel-supported Cu(OH)2. Copper peroxo complexes with different activities were identified. The reaction is molecular without radical formation. The mechanisms of H2O2 decomposition are discussed. |
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