Theoretical investigation of resonance Raman scattering of dye molecules absorbed on semiconductor surfaces

A method in time domain is proposed to investigate resonance Raman spectra of absorbed molecules on semiconductor surfaces. The charge transfer at the molecule-surface interface is incorporated with the use of an Anderson-Newns type Hamiltonian, where the surface continuum state is dealt with an expansion of Legendre polynomials for fast numerical convergence. From a model test, it is found that the intensities of Raman modes in the sole molecule generally decrease as the molecule-surface interaction is switched on, except that the energy gaps between the molecular excited state and the bottom of the band are at special values. New Raman peaks which are not observed in the sole molecule, however, appear and are greatly enhanced. The enhancement depends on the electronic coupling and the energy gap. It is also highly sensitive to the mode-specific reorganization energy in the charge transfer state, and a thousand times enhancement can be obtained at a certain reorganization energy. The corresponding electron dynamics is revealed by the population decay from the absorbed molecule.