A concise approach to the dalesconol skeleton |
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Authors: | Fan Yukai Feng Pengju Liu Mao Pan Hongjie Shi Yian |
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Affiliation: | Beijing National Laboratory of Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. |
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Abstract: | A rapid approach to the skeleton of dalesconol A and B, unprecedented immunosuppressants, has been achieved through a convergent strategy featuring a carbocation-mediated dearomatization-cyclization and a following one-pot consecutive operation. |
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