Synthesis of 2-silyl substituted phospharuthenocenes and an elaboration into the first phospharuthenocene-phosphine |
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Authors: | Carmichael Duncan Mathey François Ricard Louis Seeboth Nicolas |
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Institution: | Laboratoire Hétéroéléments et Coordination, UMR CNRS 7653, DCPH Ecole Polytechnique, 91128 Palaiseau, France. Duncanc@mars.polytechnique.fr |
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Abstract: | A 1,5] shift protocol transiently hindering the 2-position of phospholide anions provides an access to sterically unencumbered phospharuthenocenes and the first phospharuthenocene-phosphine. |
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