Unexpected formation and structural characterisation of a novel rhodium B12 analogue |
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| Authors: | Bröring Martin Tejero Esther Cónsul Pfister Andreas Brandt Carsten D Pérez Torrente Jesús J |
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| Institution: | Institut für Anorganische Chemie, Universit?t Würzburg, Am Hubland, D-97074 Würzburg, Germany. Martin.Broering@mail.uni-wuerzburg.de |
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| Abstract: | The metalation reactions of the 2,2'-bidipyrrin 4 with different rhodium(I) precursors yield the complexes 5 and 6 and the unusual corrinoid 7, depending only on the type of the ancillary ligand employed. |
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