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A cyclic hexacopper(II) fluoro complex that encapsulates two fluoride anions
Authors:Liu Xiaoming  McLaughlin Abbie C  de Miranda Marcelo P  McInnes Eric J L  Kilner Colin A  Halcrow Malcolm A
Institution:Department of Chemistry, University of Leeds, Woodhouse Lane, Leeds, UK LS2 9JT.
Abstract:The complex Cu3(HpztBu)4(mu-pztBu)2(mu-F)2(mu 3-F)]2]F2 (HpztBu = 35]-tert-butylpyrazole) has a cyclic, C2v-symmetric hexacopper core. The two non-coordinated F- anions are encapsulated within cavities formed by three HpztBu ligands.
Keywords:
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