Mechanochemical assembly of hydrogen bonded organic-organometallic solid compounds |
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| Authors: | Braga Dario Maini Lucia Polito Marco Mirolo Laurent Grepioni Fabrizia |
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| Institution: | Dipartimento di Chimica G. Ciamician, Università di Bologna, Via Selmi 2, 40126 Bologna, Italy. dbraga@ciam.unibo.it |
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| Abstract: | Solvent-free reactions with molecular systems have been exploited to prepare hybrid organic-organometallic solids: grinding of the complex Fe(eta 5-C5H4COOH)2] with solid bases B generates quantitatively the corresponding hydrogen bonded salts Fe(eta 5-C5H4COOH)(eta 5-C5H4COO)]HB] (B = 1,4-diazabicyclo2.2.2]octane, 1,4-phenylenediamine); gas-solid reactions are also possible with volatile bases. |
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