Synthesis and structure of a novel supramolecular Zn3Co8 assembly containing a linear Zn3 core |
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| Authors: | Zhang Lilu Jones Richard A Lynch Vincent M |
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| Institution: | University of Texas at Austin, Chem & Biochem Dept, University Station A5300, Austin, Texas 78712-0165, USA. |
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| Abstract: | Reaction of Zn(OAc)(2).2H2O (OAc = acetate) with LH2 in THF followed by reaction with Co2(CO)8 yields the novel supramolecular assembly Zn3L2(OAc)2Co2(CO)6](4).0.5CH2Cl2, which was characterized by X-ray diffraction (LH2 = (CH2)3(N=CH-2-OH-5-C identical to CSiMe3C6H3)2 or N,N'-propylenebis(2-hydroxy-5-trimethylsilylethynl-1-aldimine). |
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