A novel dicationic phenoxaphosphino-modified xantphos-type ligand--a unique ligand specifically designed for a high activity,selectivity and recyclability |
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Authors: | Bronger Raymond P J Silva Silvana M Kamer Paul C J van Leeuwen Piet W N M |
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Affiliation: | Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands. |
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Abstract: | A novel phenoxaphosphino-modified ligand has been prepared and successfully employed in the rhodium catalysed hydroformylation of 1-octene in ionic liquids showing unprecedented high selectivity and activity without detectable rhodium or phosphorus leaching during recycling experiments. |
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