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A novel dicationic phenoxaphosphino-modified xantphos-type ligand--a unique ligand specifically designed for a high activity,selectivity and recyclability
Authors:Bronger Raymond P J  Silva Silvana M  Kamer Paul C J  van Leeuwen Piet W N M
Affiliation:Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands.
Abstract:A novel phenoxaphosphino-modified ligand has been prepared and successfully employed in the rhodium catalysed hydroformylation of 1-octene in ionic liquids showing unprecedented high selectivity and activity without detectable rhodium or phosphorus leaching during recycling experiments.
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