The first observation of four-electron reduction in [60]fullerene-metal cluster self-assembled monolayers (SAMs) |
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| Authors: | Cho Youn-Jaung Song Hyunjoon Lee Kwangyeol Kim Kyuwon Kwak Juhyoun Kim Sehun Park Joon T |
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| Institution: | Department of Chemistry, School of Molecular Science (BK21), Korea Advanced Institute of Science and Technology, Daejeon 305-701, Korea. |
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| Abstract: | Self-assembled monolayers (SAMs) of a mu 3-eta 2:eta 2:eta 2-C60 triosmium cluster complex Os3(CO)8(CN(CH2)3Si(OEt)3)(mu 3-eta 2:eta 2:eta 2-C60) (2) on ITO or Au surface exhibit ideal, well-defined electrochemical responses and remarkable electrochemical stability being reducible up to tetranionic species in their cyclic voltammograms. |
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