Nucleophilic substitution of alkylchlorodihydro[60]fullerenes: thermodynamic stabilities of alkylated C60 cation intermediates |
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| Authors: | Kitagawa Toshikazu Lee Yangsoo Hanamura Masaaki Sakamoto Harumi Konno Hirofumi Takeuchi Ken'ichi Komatsu Koichi |
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| Affiliation: | Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan. kitagawa@scl.kyoto-u.ac.jp |
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| Abstract: | Thermodynamic stabilities of alkylated C60 cations (RC60+) were determined based on the activation free energies of SN1 solvolysis of the title compounds, indicating that these cations have stabilities comparable to that of the tert-butyl cation. |
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