| meso-三嗪取代苯基卟啉的简单一锅合成 |
| |
| 引用本文： | 肖深初,郑良彬,谢文忠,林伟英,李庆宏,郭灿城.meso-三嗪取代苯基卟啉的简单一锅合成[J].高等学校化学学报,2009,30(3):478-482. |
| |
| 作者姓名： | 肖深初 郑良彬 谢文忠 林伟英 李庆宏 郭灿城 |
| |
| 作者单位： | 湖南大学化学化工学院,长沙,410082 |
| |
| 摘 要： | 报道一种以羟基卟啉与三嗪和其它亲核试剂为原料一锅法高产率合成不对称多取代三嗪卟啉化合物的简单方法. 研究了2,4,6-三氯三嗪与羟基卟啉、醇和胺通过分级亲核取代反应合成不对称2,4,6-取代三嗪卟啉的方法和反应条件. 以2,4,6- 三氯三嗪和5-(4-羟基)苯基-10,15,20-三苯基卟啉反应生成卟啉单取代二氯三嗪, 然后进一步与醇或胺反应合成了7个三嗪卟啉新化合物, 产物经元素分析, MS, 1H NMR和UV-Vis进行结构表征.
|
| 关 键 词： | 卟啉 三嗪 一锅法合成 |
| 收稿时间： | 2008-09-01 |
Simple One-pot Synthesis of Triazine-porphyrins |
| |
| XIAO Shen-Chu,ZHENG Liang-Bin,XIE Wen-Zhong,LIN Wei-Ying,LI Qing-Hong,GUO Can-Cheng.Simple One-pot Synthesis of Triazine-porphyrins[J].Chemical Research In Chinese Universities,2009,30(3):478-482. |
| |
| Authors: | XIAO Shen-Chu ZHENG Liang-Bin XIE Wen-Zhong LIN Wei-Ying LI Qing-Hong GUO Can-Cheng |
| |
| Institution: | College of Chemistry & Chemical Engineering;Hunan University;Changsha 410082;China |
| |
| Abstract: | A series of substituted triazine-tetraphenylporphyrins were synthesized from the reaction of 5-4-(3,5-dichloro-triazine-1-oxygen)]phenyl-10,15,20-triphenylporphyrin with amines or alcohols.A new simple one-pot synthetic method from the reaction of the tetraphenylporphyrin with hydroxyl group and 2,4,6-trichloro-1,3,5-triazine and other nucleophiles was studied.The researches show that amines or alcohols substitute selectively the one of two chlorine atoms in 5-4-(3,5-dichloro-triazine-1-oxygen)]phenyl-10,... |
| |
| Keywords: | Porphyrin 2 4 6-Trichloro-1 3 5-triazine One-pot synthesis Triazine-porphyrin |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
| 点击此处可从《高等学校化学学报》下载免费的PDF全文 |
|
