Spontaneous assembly of a nine-vertex lithium framework encapsulating the peroxide dianion |
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| Authors: | Coles Martyn P Hitchcock Peter B |
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| Affiliation: | Department of Chemistry, University of Sussex, Falmer, Brighton, UK. m.p.coles@sussex.ac.uk |
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| Abstract: | Investigation of the structure of the lithiated bicyclic guanidine 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine (hppH) has led to the reproducible isolation of compounds containing the 'Li9(hpp)7(O2)' core, in which a peroxide dianion has been encapsulated within a mono-capped, cubic array of lithium ions. |
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