Nitrophenylmethane and nitromethane complexes of copper(I) with tertiary phosphines or heterocyclic nitrogen donors and some of their oxidation products |
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| Affiliation: | 1. Department of Chemistry, Faculty of Arts and Sciences, Bursa Uludag University, Bursa 16059, Turkey;2. Department of Biology, Faculty of Arts and Sciences, Bursa Uludag University, Bursa 16059, Turkey;3. Department of Chemistry, Faculty of Science, Gebze Technical University, Gebze, Kocaeli 41400, Turkey |
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| Abstract: | Mixed copper(I) complexes with nitrophenylmethane (NPMH) of the following stoicheiometries Cu(NPM)L2 (L = PPh3, pyridine; L−L = bis(diphenylphosshino)methane, 2,2′-bipyridine), (CuNPM)2 (L−L)3 (L−L = 1,2-bis(diphenylphosphino)ethane) and [Cu(L−L)2]NPM (L−L = 1,10-phenanthroline) have been isolated and characterized. The corresponding phosphine complexes of the nitromethane are also described. In the complexes of the nitrophenylmethane cleavage of the PhCH = group occurs easily, while the NO2 group remains bounded to the copper atom as nitrite ligand. |
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