Efficient protiodesilylation of unactivated C(sp3)-SiMe2Ph bonds using tetrabutylammonium fluoride |
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| Authors: | Heitzman Cheryl L Lambert William T Mertz Eric Shotwell J Brad Tinsley Jennifer M Va Porino Roush William R |
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| Affiliation: | Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055, USA. |
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| Abstract: | [reaction: see text] The protiodesilylation of unactivated C(sp3)-SiMe2Ph bonds proceeds efficiently by treatment with tetrabutylammonium fluoride in wet DMF or THF via isolable dimethylsilanol intermediates. |
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