Synthetic,spectroscopic, thermal,and structural studies of antimony(III) bis(pyrrolidinedithiocarbamato)alkyldithiocarbonates |
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Authors: | H P S Chauhan Abhilasha Bakshi |
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Institution: | (1) School of Chemical Sciences, Devi Ahilya University, Takshashila Campus, Khandwa Road, Indore, 452001, India |
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Abstract: | An account of the synthesis, spectroscopic, thermal and structural behavior of antimony(III) bis(pyrrolidinedithiocarbamato)alkyldithiocarbonates
is presented. The reaction of antimony(III) bis(pyrrolidinedithiocarbamate) chloride with potassium organodithiocarbonate
in equimolar ratio yielded the corresponding mixed derivatives of the type (CH2)4NCS2]2SbS2COR where R = Me, Et, Pr
n
, Pr
i
, Bu
n
, and Bu
i
]. These newly synthesized complexes have been characterized by physicochemical molecular weight determination, melting points,
and elemental analysis], spectral UV, IR, far-IR, NMR (1H and 13C)], thermal TG, DTA, and FAB+ mass], and structural powder XRD and SEM] studies. Analytical studies leads to purity and structural properties of the synthesized
complexes on the other hand powder X-ray diffraction and SEM studies show that multiphase, polycrystalline, and rod-shaped
complexes have been formed having nanorange crystallite size and monoclinic crystal system. |
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Keywords: | |
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