Synthesis and characterization of a new coordination compound of gold(III) with triphenylarsine oxide(TPAsO) |
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Authors: | Gong Yuqiu Xia Shihua |
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Affiliation: | Department of Chemistry, Hangzhou University, Hangzhou, China |
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Abstract: | A new solid coordination compound of the type 1:1 of TPAsO to gold(III) was prepared firstly by means of the extraction method, but only the coordination compound of the type 2:1 was obtained by the method of direct synthesis. It was found in polar solvents that the 1:1 type coordination compound could transform to that of the 2:1 type slowly. By the data of thermoanalyses, a mechanism was suggested for thermal decomposition of the above two coordination compounds. |
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