| Redox Polymerization of Methyl Methacrylate in the Fluorous Triphasic System |
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| 引用本文： | Shi Zhen CHEN Yun Peng BAI Zhao Long LI. Redox Polymerization of Methyl Methacrylate in the Fluorous Triphasic System[J]. 中国化学快报, 2006, 17(2): 258-260 |
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| 作者姓名： | Shi Zhen CHEN Yun Peng BAI Zhao Long LI |
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| 作者单位： | Shi Zhen CHEN，Yun Peng BAI，Zhao Long LI Department of Chemistry，Tsinghua University，Beijing 100084 |
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| 基金项目： | Acknowledgments We thank the central laboratory of the Department of Material, Tsinghua University for helping in the GPC analysis. |
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| 摘 要： | Fluorous-phase chemistry is currently a topic of considerable interest1-6. Since fluoroustriphasic reactions were first described by the Curran and co-workers7, this triphasicsystem has been widely used for detagging7,8 and phase-vanishing reactions9-11. …
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| 关 键 词： | 三相氟系统 氧化还原聚合 甲基丙烯酸甲酯 过氧化苯甲酰 N N-二甲基苯胺 引发剂 |
| 收稿时间： | 2005-07-14 |
Redox Polymerization of Methyl Methacrylate in the Fluorous Triphasic System |
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| Shi Zhen CHEN,Yun Peng BAI,Zhao Long LI. Redox Polymerization of Methyl Methacrylate in the Fluorous Triphasic System[J]. Chinese Chemical Letters, 2006, 17(2): 258-260 |
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| Authors: | Shi Zhen CHEN Yun Peng BAI Zhao Long LI |
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| Abstract: | Methyl methacrylate (MMA) was polymerized by using of benzoyl peroxide (BPO) andN, N-dimethylaniline (DMA) as an redox initiator in fluorous triphasic system at room temperature.The polymerization was occurred in both initiator layer and monomer layer in a U-tube. It wasfound that PMMA obtained from the initiator layer with relatively narrow polydispersity.(PDI =1.38) |
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| Keywords: | Fluorous triphasic system redox polymerization methyl methacrylate. |
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