Simple Synthesis of a Chlorin - Fullerene Dyad with a Novel Ring-Closure Reaction |
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Authors: | Montforts Kutzki |
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Institution: | Institut für Organische Chemie der Universit?t FB2 Biologie/Chemie Postfach 330440, 28334 Bremen (Germany). |
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Abstract: | To model the photosynthetic reaction center, the chlorin - fullerene dyad 1 was synthesized in a one-pot reaction from a linear tetrapyrrole and C(60). It is the first dyad of this type which contains a fullerene and a chlorin unit, the chromophore of naturally occurring photosynthetic systems. |
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