Abstract: | A facile synthesis of benzoh ]quinolines has been developed via improved Combes reaction. A combination of silica gel, p ‐toluenesulfonic acid and phosphorus pentoxide was utilized to promote the condensation of 1‐naphthylamines with 1,3‐diketones under solvent free conditions. In this case, silica gel was used as reaction media, p ‐toluenesulfonic acid and phosphorus pentoxide were acted as catalyst and dehydrating agent, respectively. |