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Carbon Tetrabromide/Triphenylphosphine‐Activated Beckmann Rearrangement of Ketoximes for Synthesis of Amides
Abstract:An efficient Beckmann rearrangement of ketoximes was developed using carbon tetrabromide/triphenylphosphine as an organocatalyst without addition of any acids or metals. The reaction showed good functional group tolerance and gave various amides in moderate to good yields.
Keywords:Beckmann rearrangement  oganocatalyst  ketoximes  amides
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