Catalyst‐free Synthesis of 5‐Arylimidazo[1,2‐c]quinazoline Derivatives in Ionic Liquids |
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Abstract: | The reaction of 2‐(4,5‐diphenyl‐1H‐imidazol‐2‐yl)aniline and aromatic aldehyde was treated in ionic liquids under catalyst‐free condition and gave dehydrogenated 5‐aryl‐2,3‐diphenylimidazo1,2‐c ]quinazolines. The same reaction gave un‐aromatized 5‐aryl‐2,3‐diphenyl‐5,6‐dihydroimidazo1,2‐c ]quinazoline derivatives while it was controlled in an inert gas. This procedure approach to imidazo1,2‐c ]quinazolines has the advantages of milder reaction conditions, one‐pot, catalyst free, high yields, and environmentally benign. |
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