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Vibrational spectroscopic studies on the en-Td-type benzene clathrates: M(ethylenediamine)M′(CN)4·2C6H6 (M=Mn or Cd,M′=Cd or Hg)
Authors:Kasap  Ergün  Kantarci  Ziya
Institution:(1) Fen-Edebiyat Fakültesi, Gazi Üniversitesi, Teknikokullar, 06500 Ankara, Turkey
Abstract:IR spectra of Mn(en)M(CN)4·2C6H6 (M=Cd or Hg), and IR and Raman spectra of Cd(en)M(CN)4·2C6H6 (M=Cd or Hg) clathrates are reported. The spectral features suggest that the first two compounds are similar in structure to the later two Td-type clathrates.
Keywords:en-Td-type clathrate  inclusion compounds  ethylenediamine  IR spectra  Raman spectra
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