Suzuki coupling catalyzed by a homoleptic Pd(I)-Pd(I) solvento complex |
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| Authors: | Xiaoyan Han T. S. Andy Hor |
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| Affiliation: | Department of Chemistry, National University of Singapore, 3 Science Drive 3, Kent Ridge, Singapore 117543, Singapore |
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| Abstract: | The PdI-PdI bonded complex [Pd2(CH3CN)6][SbF6]2 is catalytically active towards Suzuki cross-coupling reactions of aryl bromides or chlorides with various arylboronic acids under mild conditions giving good to excellent yields. Its performance is enhanced by the introduction of stoichiometric or limited phosphines. The effects of different ligands, metal oxidation states [Pd(II), Pd(I) Pd(0)], bases and solvents have been examined. |
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| Keywords: | Suzuki coupling Palladium Dinuclear Homoleptic Catalyst |
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