Dendrimers with 1, 3, 5‐Trisilacyclohexane as Core Unit |
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| Authors: | Eugen Weisheim Beate Neumann Hans‐Georg Stammler Norbert W Mitzel |
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| Institution: | Centre for Molecular Materials CM2, Chair of Inorganic and Structural Chemistry, Faculty of Chemistry, Bielefeld University, Universit?tsstra?e 25, 33615Bielefeld, Germany |
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| Abstract: | 1, 1, 3, 3, 5, 5‐Hexavinyl‐1, 3, 5‐trisilacylohexane Si(CH=CH2)2CH2]3 was synthesized and hydrosilylated with trichlorosilane to afford the first generation of a dendrimer. Conversion of this molecule with 18 Si–Cl functions on its surface with an excess of vinylmagnesium bromide yielded the 18‐fold vinylated dendrimer. The new compounds were identified by elemental analyses, multi‐nuclear NMR spectroscopy, and mass spectrometry. Crystal structures were obtained for Si(CH=CH2)2CH2]3 and Si(CH2–CH2SiCl3)2CH2]3. |
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| Keywords: | Dendrimer 1 3 5‐Trisilacyclohexane Hydrosilylation Vinylation |
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