A Room‐Temperature Luminescent AgCF3COO Complex Consisting of Cationic Complex Chains and Anionic Guests |
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| Authors: | Jing Han Yong Di Zhang Zhong Yu Xiang He Bing Jin |
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| Affiliation: | 1. Department of Material Physics and Chemistry, Xi'an University of Technology, No 5 South Jinhua Road, Xi'an, Shaanxi, 710048, P. R. China;2. Department of Chemistry, Xi'an University of Technology, No 5 South jinhua Road, Xi'an, Shaanxi, 710048, P. R. China;3. Department of Chemistry, Shanghai University, 99 Shangda Road, Shanghai, 200444, P. R. China;4. School of Aeronautics, Northwestern Polytechnical University, 127 West Youyi Road, Xi'an, Shaanxi, 710072, P. R. China |
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| Abstract: | Reaction of p‐phenylenediacetonitrile (p‐phda) with AgCF3COO afforded the coordination polymer, {[Ag2(p‐phda)2] [Ag4(CF3COO)6]}n ( 1 ), where the 1D cationic [Ag2(p‐phda)2]2+ chain acts as host and the anionic [Ag4(CF3COO)6]2– as guest molecules occupy the channel between neighboring host chains. This is a rare crystal example of AgCF3COO complex consisting of cationic complex chains and anionic guests. In addition, complex 1 exhibits luminescence at room temperature in solid state. |
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| Keywords: | Cationic complex chains Silver Anionic guests Luminescence |
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