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Structure formation under negative pressures
Authors:V. I. Kosyakov
Affiliation:(1) Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivistok, Russia
Abstract:IR and Raman spectroscopy are used to study cubic and orthorhombic modifications of Sb2O3. Vibrational spectra are calculated in the approximation of density functional theory; the bands are assigned. Based on the assignment made, vibrational spectra of the α-Sb3O2F5 compound are analyzed.
Keywords:antimony(III) oxide  DFT  IR  Raman  vibrational spectroscopy
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