| Synthesis andCrystal Structure of{[Mn（H2O）4（3,3′—azpy）]（3,3′—azpy）3（PF6）2}n |
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| 引用本文： | 李宝龙,曹正白,王寿武,徐正,郁开北.Synthesis andCrystal Structure of{[Mn（H2O）4（3,3′—azpy）]（3,3′—azpy）3（PF6）2}n[J].结构化学,2002,21(3):292-295. |
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| 作者姓名： | 李宝龙 曹正白 王寿武 徐正 郁开北 |
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| 作者单位： | 李宝龙,曹正白,王寿武(Department of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, China);徐正(Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China);郁开北(Chengdu Centre of Analysis and Measurement, Academia Sinica, Chengdu 610041, China)
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| 基金项目： | 江苏省重点实验室基金 |
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| 摘 要： | The complex {Mn(H2O)4(3, 3?-azpy)](3, 3?-azpy)3(PF6)2}n (3, 3?-azpy = 3, 3?- azobispyridine) has been synthesized and characterized. The crystal (C40H40F12MnN16O4P2, Mr = 1153.76) belongs to the triclinic system, space group P ī with the following crystallographic parameters: a = 10.761(2), b = 11.040(2), c = 23.365(4) ?, ( = 85.52(1), ( = 82.69(1), ( = 70.44(1)°, V = 2592.5(8) ?3, Dc = 1.478 g/cm3, ((MoK() = 4.16 cm-1, F(000) = 1174, Z = 2, final R = 0.0493 and wR = 0.1158 for the observed reflections (I > 2.00((I)). The X-ray analysis revealed that manganese(Ⅱ) cation coordination environment is a distorted octahedral geometry, and the Mn2+ cation is coordinated by four oxygen atoms of water in the equatorial plane, while the two nitrogen atoms of 3, 3?-azpy occupy the axial positions. The complex forms a one-dimensional chain structure via 3, 3?-azpy bridging ligand.
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| 关 键 词： | 锰配合物 合成 晶体结构 偶氮双吡啶 |
Synthesis and Crystal Structure of{[Mn(H2O)4(3, 3′-azpy)](3, 3′-azpy)3(PF6)2}n |
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| Abstract: | The complex {Mn(H2O)4(3, 3?-azpy)](3, 3?-azpy)3(PF6)2}n (3, 3?-azpy = 3, 3?- azobispyridine) has been synthesized and characterized. The crystal (C40H40F12MnN16O4P2, Mr = 1153.76) belongs to the triclinic system, space group P ī with the following crystallographic parameters: a = 10.761(2), b = 11.040(2), c = 23.365(4) ?, ( = 85.52(1), ( = 82.69(1), ( = 70.44(1)°, V = 2592.5(8) ?3, Dc = 1.478 g/cm3, ((MoK() = 4.16 cm-1, F(000) = 1174, Z = 2, final R = 0.0493 and wR = 0.1158 for the observed reflections (I > 2.00((I)). The X-ray analysis revealed that manganese(Ⅱ) cation coordination environment is a distorted octahedral geometry, and the Mn2+ cation is coordinated by four oxygen atoms of water in the equatorial plane, while the two nitrogen atoms of 3, 3?-azpy occupy the axial positions. The complex forms a one-dimensional chain structure via 3, 3?-azpy bridging ligand. |
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| Keywords: | crystal structure one-dimensional chain manganese complex azobispyridine |
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