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Pillared clays as efficient catalysts for cyclohexanol oxidation
Authors:Kurian Manju and Sankaran Sugunan
Institution:(1) Department of Applied Chemistry, Cochin University of Science and Technology, Kochi-22, India;(2) Department of Applied Chemistry, Cochin University of Science and Technology, Kochi-22, India
Abstract:Summary Iron, aluminium and mixed iron aluminium pillared clays were prepared by partial hydrolysis method and doped with 10% V and Mo. The samples were characterised by XRD, FTIR and surface area and pore volume measurements. Oxidation of cyclohexanol with hydrogen peroxide was done as probe reaction to test catalytic activity. Iron pillared systems exhibited maximum activity. The effects of various reaction variables on the reaction were studied.
Keywords:oxidation  catalysis  cyclohexanone  Pillared clays  cyclohexanol
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