Synthese et reactivite d'organomagnesiens perfluores. V.[1] Synthese et identification de nouveaux composes perfluoroalkyles du mercure a chaine longue. |
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Authors: | Jean-Pierre Zissis Patrice Moreau Auguste Commeyras |
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Affiliation: | Laboratoire de Chimie Organique, E.R.A. No 555, Université des Sciences et Techniques du Languedoc - Place E. BATAILLON - 34060 - Montpellier - Cédex France |
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Abstract: | The reaction of mercuric salts HgY2 or organic mercuric compounds RHHgX with long chain perfluorinated Grignard reagents RFMgBr leads to a series of new perfluoroalkyl mercury derivatives with the general formula RFHgZ (RF=C4F9, C6F13, C8F17 ; Z=RF,RH,Y with Y = I,Br,Cl, NO3,OCOCH3,OCOCF3).The synthesis of these organomercuric compounds is described, and their spectroscopic properties are reported. |
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