Reaktionen des fluorcyans,FCN |
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| Authors: | Helmut Schachner Wolfgang Sundermeyer |
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| Institution: | Anorganisch-chemisches Institut der Universität Heidelberg, Im Neuenheimer Feld 270, D-6900 Heidelberg B.R.D. |
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| Abstract: | By reaction of cyanogen fluoride with fluorine compounds like COF2, SF4, SOF4 and HF in the presence of nucleophilic catalysts the addition products CF3NCO, CF3NSF2, CF3NSOF2 and CF3NH2 could be obtained together with polymer and copolymer products of FCN. By rearrangement and further reaction of intermediates also CF3OCOF, (CF3)2NCOF and the hitherto unknown compounds CF3N(CN)2 and F2CNCF2NSOF2 are formed. |
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