Nitroxide chemistry. Part XIX. Reaction of bistrifluoromethyl nitroxide with diphenylketene and related compounds (Ph2CHCOX,X OH,Cl, NH2) |
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Authors: | Ronald E Banks Robert N Haszeldine Michael B Murray |
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Institution: | Department of Chemistry, The University of Manchester Institute of Science and Technology, Manchester M60 1QD Great Britain |
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Abstract: | The following reactions have been accomplished: 2(CF3)2NO· + Ph2CCO → Ph2CON(CF3)2]CO2N(CF3)2 → (on hydrolysis) Ph2CON(CF3)2]CO2H; 2 (CF3)2NO· + Ph2CHCOX → (CF3)2NOH + Ph2CON(CF3)2]COX (X OH, Cl,NH2). |
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Keywords: | To whom enquiries should be addressed |
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