Chemie polyfunktioneller liganden LXIII. Adamantankäfigverbindungen mit den heteroelementen arsen,stickstoff und silizium |
| |
| Authors: | Jochen Ellermann Martin Lietz |
| |
| Institution: | Institut für Anorganische Chemie der Universität Erlangen-Nürnberg, Egerlandstrasse 1, D-8520 Erlangen B.R.D. |
| |
| Abstract: | The reaction of 1,1,1-tris(diiodarsinomethyl)ethane, CH3C(CH2AsI2)3 (I), with i-C3H7NH2, n-C4H9NH2, C6H5NH2, p-CH3C6H4NH2 and (CH3)3Si]2NH in the presence of (C2H5)3N as auxiliary base in THF gives the adamantane cage compounds CH3C(CH2AsNC3H7)3 (III), CH3C(CH2AsNC4H9)3 (IV), CH3C(CH2AsNC6H5)3 (V), CH3C(CH2AsNC6H4CH3)3 (VI) and CH3CCH2AsNSi(CH3)3]3 (VII). VII is also obtained in the reaction of I with NaNSi(CH3)3]2. The by-product (CH3)3SiO(CH2)4I (VIII) could be isolated in both syntheses of VII. All compounds have been characterized by mass spectrometry and infrared, Raman and 1H NMR spectroscopy. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
