Abstract: | Some reactions of amines with a perfluorovinylsulfide, (CF3)2CFSC(CF3)CFCF(CF3)2, prepared from hexafluoropropene (HFP) and sulfur [1] are compared to reactions of the same amines with the thermodynamic dimer of HFP, (CF3)2CCFCF2CF3. Many new ketenimines, eneamines, amidines, nitriles, and quinoline derivatives are reported. |