首页 | 本学科首页   官方微博 | 高级检索  
     检索      


The molecular structure of [dimethyl(phenyl)silyl]tris(trimethylsilyl)methane
Authors:Colin Eaborn  Peter B Hitchcock  Paul D Lickiss
Institution:School of Molecular Sciences, University of Sussex, Brighton BNI 9QJ Great Britain
Abstract:The structure of the crowded molecule (Me3Si)3C(SiMe2Ph) has been determined by single crystal X-ray diffraction. The steric strain manifest itself mainly in lengthening of the Me3SiC and Me2PhSiC bonds (average length 1.920(6) ,ac>A?) and closing up of the CSiC angles within the Me3Si and Me2PhSi groups (average 105.2(10)°), with correspondingly large C(1)SiC angles (113.5(13)°; C(1) is the central carbon atom).
Keywords:
本文献已被 ScienceDirect 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号