Zur bildung neuer linearer und cyclischer isopren-dimerer an titan-katalysatoren mit sauerstoff-chelatliganden |
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| Authors: | Heindirk tom Dieck Hartmut Müller |
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| Institution: | Institut für Anorganische und Angewandte Chemie der Universität Hamburg, Martin-Luther-King-Platz 6, D-2000 Hamburg 13 B.R.D. |
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| Abstract: | L2ReH7 (L=PPh3) reacts with 3,3-dimethylbutene and benzene (the latter being used as solvent) to give the dihydridocyclohexadienyl compound L2(η5-C6H7)ReH2, the X-ray crystal structure of which is reported. With deuteriobenzene, the reaction gives a product which is partially deuteriated at the rhenium atom and in the ortho-positions of the phosphine ligands. |
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