Correlation entre structure,conductivite ionique et proprietes thermodynamiques dans la serie des halogenofluorures de l'etain II |
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Authors: | P. Claudy J.M. Letoffe S. Vilminot W. Granier Z. Al Ozaibi L. Cot |
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Affiliation: | Laboratoire de Thermochimie Minérale associé au C.N.R.S. (L.A. No 116) Institut National des Sciences Appliquées de Lyon 20, avenue Albert Einstein - 69621 Villeurbanne Cedex France;Laboratoire de Chimie Minérale Appliquée, Chimie des Matériaux associé au C.N.R.S. (E.R.A. 314) Ecole Nationale Supérieure de Chimie 8 rue de l''Ecole Normale - 34075 Montpellier Cedex France |
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Abstract: | Fluorides and some mixed halogen fluorides of tin(II) have been studied by X-ray diffraction, differential scanning calorimetry, and conductimetry. From a consideration of structural properties a relationship has been established between the co-ordination sphere, ionic mobility and entropy of fusion. |
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