The hydrolysis of bromodifluoromethyltriphenylphosphonium bromide [1] |
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| Authors: | R.M. Flynn R.G. Manning R.M. Kessler D.J. Burton S.W. Hansen |
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| Affiliation: | National Institutes of Health, Department of Nuclear Medicine, Bethesda, Maryland 20205 U.S.A.;Department of Chemistry, University of Iowa, Iowa City, Iowa 52242 U.S.A. |
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| Abstract: | Hydrolysis of [Ph3CF2Br]Br? afforded a high yield of bromodifluoromethane and triphenylphosphine oxide. Hydrolysis in the presence of a radioactive isotope of bromine or sodium iodide gave unequivocal evidence that the mechanism for this reaction proceeds through a difluorocarbene intermediate. |
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| Keywords: | To whom correspondence should be addressed. |
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