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Rapid separation and determination of mercury
Authors:Kressin I
Institution:University of California, Los Alamos Scientific Laboratory Los Alamos, New Mexico 87544, U.S.A.
Abstract:An analytical procedure is described for the separation of mercury(II) by extraction into n-octanol from sulphuric acid solution and then back-extraction as the tetraiodo complex. The mercury is determined by measuring the absorbance of this complex at 322 nm (molar absorptivity 1.95 x 10(3) l.mole(-1).cm(-1)). The procedure is applicable to samples containing copper; the effects of a wide variety of other impurities are tabulated.
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