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Equations for the Magnetization Modes in a System Having a Quadruple Nucleus with the Spin S = 1
Authors:G S Kupriyanova
Institution:(1) Kaliningrad State University, 14 Nevskii Str., Kaliningrad, 236040, Russia
Abstract:Within the framework of the method of a density matrix, differential equations are obtained that describe the evolution of the modes of magnetization <Î+>, <Î+Scirc z >, and <Î+Scirc z 2> for a spin system containing a nucleus with a 1/2 spin connected scalarly with the quadruple nucleus of the spin S = 1 in the presence of crossdashcorrelation between the dipole IdashSdashinteractions, anisotropy of the chemical shift of the I and S nuclei, and quadruple interaction of the S nucleus. The equations are used for analysis of the evolution of the intensities of each line in the triplet of the Raman spectrum of the 1/2 spin. Expressions for the times of crossdashrelaxation and the times of transverse relaxation of each of the lines of the triplet are obtained.
Keywords:magnetization modes  function of spectral density  crossdashcorrelation" target="_blank">gif" alt="dash" align="MIDDLE" BORDER="0">correlation  crossdashrelaxation" target="_blank">gif" alt="dash" align="MIDDLE" BORDER="0">relaxation  triplet coherence  spindashspin interaction" target="_blank">gif" alt="dash" align="MIDDLE" BORDER="0">spin interaction  quadruple interactions  anisotropy of a chemical shift  dipole interactions
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