Reaction mechanism studies on isoquinoline with hydroxyl radical in aqueous solutions |
| |
| Authors: | Dazhang Zhu Shilong Wang Xiaoyu Sun Yaming Ni Side Yao |
| |
| Institution: | (1) Department of Chemistry, Tongji University, Shanghai, 200092, China;(2) School of Life Science and Technology, Tongji University, Shanghai, 200092, China;(3) Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, 201800, China |
| |
| Abstract: | The reaction mechanism between isoquinoline and ·OH radical in aqueous dilute solutions under different conditions was studied
by pulse radiolysis. The main characteristic peaks in these transient absorption spectra were attributed and the growth-decay
trends of several transient species were investigated. Under neutral or alkaline conditions, the reaction of ·OH radical and
isoquinoline produces OH-adducts with respective rate constants of 3.4 × 109 and 6.6 × 109 mol−1 · dm3 · s−1 while under acidic conditions, the isoquinoline was firstly protonated and then ·OH added to the benzene ring and produced
protonated isoquinoline OH-adducts with a rate constant of 3.9 × 109 mol−1 · dm3 · s−1. With a better understanding on radiolysis of isoquinoline, this study is of help for its degradation and for environmental
protection.
__________
Translated from Journal of Fudan University (Natural Science), 2006, 45(6): 774–778 8BD1;81EA: 590D;65E6;5B66;62A5;(自然科学版)] |
| |
| Keywords: | isoquinoline pulse radiolysis transient absorption spectra hydroxyl radical |
| 本文献已被 万方数据 SpringerLink 等数据库收录！ |
|
