| 基于2，3，5，6-四氟对苯二甲酸构筑的两个超分子网络结构的合成、结构和荧光性质 |
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| 引用本文： | 冉行蕊,谢卫萍,熊艳菊,程谦,乐善堂,刘应亮.基于2，3，5，6-四氟对苯二甲酸构筑的两个超分子网络结构的合成、结构和荧光性质[J].无机化学学报,2013,29(18). |
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| 作者姓名： | 冉行蕊 谢卫萍 熊艳菊 程谦 乐善堂 刘应亮 |
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| 作者单位： | 华南师范大学化学与环境学院, 广州 510006;华南师范大学化学与环境学院, 广州 510006;华南师范大学化学与环境学院, 广州 510006;华南师范大学化学与环境学院, 广州 510006;华南师范大学化学与环境学院, 广州 510006;广州市能源转换和存储材料重点实验室, 广州 510006;华南农业大学理学院应用化学系, 广州 510642 |
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| 基金项目： | 国家自然基金（No.20971047，U0734005，21271076），广东省教育厅重点项目（No.cxzd1020），广州市科技计划项目（No.2013J4100049）。 |
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| 摘 要： | 在水热条件下合成了基于四氟对苯二甲酸的2个二维微孔配位聚合物{Cd2（IP）2（tfBDC）2（H2O）2]·H2O}n（1）和{Mn2（IP）2（tfBDC）2（H2O）2]·H2O}n（2）（tfBDC=2，3，5，6-四氟对苯二甲酸，IP=1-H-咪唑4，5-f]1，10]-菲咯啉）。二维层状结构是44-网状结构，三维超分子结构是由氢键连接相邻的二维层状结构而形成的。2个配位聚合物均用元素分析、热重分析（TGA）、粉末衍射（PXRD）、红外光谱（FT-IR）进行了表征，且对配合物1的荧光性质进行了详细的分析。
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| 关 键 词： | 配位聚合物 超分子网状结构 水热合成 荧光性质 |
| 收稿时间： | 7/8/2014 12:00:00 AM |
Syntheses, Structures, and Fluorescence of Two Supramolecular Networks Based on 2,3,5,6-Tetrafluoroterephthalate |
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| RAN Xing-Rui,XIE Wei-Ping,XIONG Yan-Ju,CHENG Qian,YUE Shan-Tang and LIU Ying-Liang.Syntheses, Structures, and Fluorescence of Two Supramolecular Networks Based on 2,3,5,6-Tetrafluoroterephthalate[J].Chinese Journal of Inorganic Chemistry,2013,29(18). |
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| Authors: | RAN Xing-Rui XIE Wei-Ping XIONG Yan-Ju CHENG Qian YUE Shan-Tang and LIU Ying-Liang |
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| Institution: | School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China;School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China;School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China;School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China;School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China;Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, Guangzhou 510006, China;College of Science, South China Agricultural University, Guangzhou 510642, China |
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| Abstract: | Two isomorphous 2D coordination polymers {Cd2(IP)2(tfBDC)2(H2O)2]·H2O}n (1) and {Mn2(IP)2(tfBDC)2(H2O)2]·H2O}n (2) tfBDC=2,3,5,6-tetrafluoroterephthalic acid, IP=1-H-imidazo4,5-f]1,10]-phenanthroline], based on tetrafluoroterephthalate, have been successfully synthesized under hydrothermal conditions. The 2D layer is 44-network. In addition, the neighboring 2D sheets are connected by hydrogen bonds into 3D supramolecular architecture. Both the complexes are characterized by elemental analyses, thermogravimetric analyses (TGA), powder X-ray diffraction patterns (PXRD), FT-IR spectroscopy. Furthermore, the luminescence property of complex 1 was also investigated in detail. |
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| Keywords: | coordination polymer supramolecular networks hydrothermal synthesis luminescent properties |
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