Reactions de cyclisation photochimique D'α-alcoxy cyclohexenones |
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Authors: | Alain Enger Alexandre Feigenbaum Jean-Pierre Pete Jean-Louis Wolfhugel |
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Abstract: | α-Ketooxetanes and α-alkylidene oxetanols are the main products of the photolysis of 2-alkoxy 2-cyclohexenones; γ-hydrogen abstraction and cyclization of the intermediate biradical are general processes for these enones. Regioselectivity of the reaction and several aspects of the photolysis of a ketooxetanes are discussed. The corresponding 2-alkoxy cross-conjugated dienones rearrange in cyclopropyl ketones when photolyzed in the same conditions. |
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