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Les α-cuprophosphonates—iii : Application à la synthése de β-cétophosphonates
Authors:F Mathey  Ph Savignac
Institution:Equipe IRCHA-CNRS, 2-8 rue Henri Dunant, B.P. n°28.94320 Thiais France
Abstract:A new, practical, synthesis of β-ketophosphonates relying on the conversion of the organolithium reagent from a dialkyl methylphosphonate into the corresponding organocopper reagent, and its reaction with acyl chlorides is described. The structure of the intermediate organocopper reagents is discussed.
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