Les α-cuprophosphonates—iii : Application à la synthése de β-cétophosphonates |
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Authors: | F Mathey Ph Savignac |
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Institution: | Equipe IRCHA-CNRS, 2-8 rue Henri Dunant, B.P. n°28.94320 Thiais France |
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Abstract: | A new, practical, synthesis of β-ketophosphonates relying on the conversion of the organolithium reagent from a dialkyl methylphosphonate into the corresponding organocopper reagent, and its reaction with acyl chlorides is described. The structure of the intermediate organocopper reagents is discussed. |
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