Synthesis of optically active forms of seudenol,the pheromone of douglas fir beetle期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Synthesis of optically active forms of seudenol,the pheromone of douglas fir beetle

Authors:	K. Mori S. Tamada M. Uchida N. Mizumachi Y. Tachibana M. Matsui

Affiliation:	Department of Agricultural Chemistry, The University of Tokyo, Yayoi 1-1-1, Bunkyo-ku, Tokyo 113, Japan

Abstract:	(R)-(+)-Seudenol (3-methylcyclohex-2-en-1-ol) and its antipode were synthesized from optically active forms of 3-iodocyclohex-2-en-1-ol by treatment with Me₂CuLi. Their absolute configurations were determined by converting (+)-3-iodocyclohex-2-en-1-ol to the known (R)-(+)-cyclohex-2-en-1-ol.

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