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Esr and endor studies of partially deuterated and chlorinated phenalenyls : New synthetic pathways |
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| Authors: | R. Biehl Ch. Hass H. Kurreck W. Lubitz S. Oestreich |
| Affiliation: | Institut für Organische Chemie der Freien Universität Berlin, Thielallee 63–67, D-1000 Berlin33, Germany |
| Abstract: | A variety of partially chlorinated and deuterated phenalenyl radicals has been produced by the reaction of the respective acenaphthylenes with chloroform as a carbenoid precursor and via thermal decomposition of some mercury carboxylates. By ESR and ENDOR-in-solution measurements the effectiveness of the different reaction paths to specifically substituted compounds has been investigated. |
| Keywords: | Institut für Molekülphysik der Freien Universität Berlin, Boltzmannstr. 10, D-1000 Berlin 33, Germany present address: Broker Physik AG, Silberstreifen, D-7512 Karlsruhe, Germany. |
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