Ground state sigmatropic and electrocyclic rearrangements in some monoterpenes: The pyrolysis of α-pinene |
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| Authors: | K.J. Crowley S.G. Traynor |
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| Affiliation: | Department of Chemistry, Trinity College, Dublin, Ireland |
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| Abstract: | Alloocimene 7, obtained via ocimene 6 by heating α-pinene 2, was further pyrolysed to a complex mixture of products derived primarily from antarafacial 1,7- and suprafacial 1,5-hydrogen migrations, and 6-eleetron disrotatory electrocyclizations. |
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| Keywords: | Present address: Glidden-Durkee P.O. Box 389 Jacksonville Florida U.S.A. |
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