Determination of the stereochemistry of isomeric steroidal 3-spiro-isoxazolidine-[2,3-d]-oxadiazoline by circular dichroism and x-ray diffraction |
| |
| Authors: | S. Colombi,G. Vecchio,G. Gottarelli,B. Samori&#x ,A.M.Manotti Lanfredi,A. Tiripicchio |
| |
| Affiliation: | Laboratorio di Chimica degli Ormoni del C.N.R., Via M. Bianco 9, Milano, Italy;Istituto di Chimica degli Intermedi, Viale Risorgimento 4, Bologna, Italy;Istituto di Chimica Generale ed Inorganica, Centro di Studio per la Strutturistica Diffrattometrica del C.N.R., Via M. D''Azeglio 85, Parma, Italy |
| |
| Abstract: | The absolute configuration of four isomeric steroidal molecules containing the isoxazolidine-[2,3-d]-oxadiazoline moiety has been determined by circular dichroism and X-ray diffraction methods. This heterocyclic system adopts a cis fused structure in which the mean planes passing through the two rings form a dihedral angle of 111°. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
