Oxidation of n-alkyl-n'-tosylhydrazines to hydroperoxides |
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Authors: | L. Caglion F. Gasparrini D. Misiti G. Palmieri |
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Affiliation: | Cattedra di Chimica Organica, Facolta'' di Farmacia, Universita'' di Roma, Italia;Istituto di Chimica Organica e Farmaceutica, Universita'' di Camerino, Italia |
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Abstract: | N-Alky-N'-tosylhydrazines upon treatment with H2O2 and Na2O2 give with high yields the corresponding aliphatic hydroperoxides. A discussion on the possible reaction mechanism which involves the formation of an “ion pair” intermediate, is reported. The reaction of tosylhydrazones carried out under simular conditions to give dihydroperoxides and other compounds is also described. |
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